Abstract
Abstract The title complex prepared through an electrophilic substitution of (11,13-diemthyl-1,4,7,10-tetraaza-10,12-cyclotridecadienato)nickel(II) bromide with p-methylbenzoyl chloride was subjected to single-crystal X-ray diffraction analysis. The analysis has revealed completion of the substitution reaction, pseudo C2 symmetry of the macrocyclic complex minus the substituent, and an essentially square planar coordination environment with slight tetrahedral distortion. The substituted p-methylbenzoyl group is tilted with respect to the least-squares plane of the conjugated six-membered chelate ring, where the dihedral angle between them is 69.2°.
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