Crossover from low-temperature to high-temperature fluctuations: Universal and nonuniversal Casimir forces of isotropic and anisotropic systems.

Abstract

We study the crossover from low-temperature to high-temperature fluctuations including Goldstone-dominated and critical fluctuations in confined isotropic and weakly anisotropic O(n)-symmetric systems on the basis of a finite-size renormalization-group approach at fixed dimension d introduced previously [V. Dohm, Phys. Rev. Lett. 110, 107207 (2013)PRLTAO0031-900710.1103/PhysRevLett.110.107207]. Our theory is formulated within the φ^{4} lattice model in a d-dimensional block geometry with periodic boundary conditions. We calculate the finite-size scaling functions F^{ex} and X of the excess free-energy density and the thermodynamic Casimir force, respectively, for 1≤n≤∞,2<d<4. Exact results are derived for n→∞. Applications are given for L_{∥}^{d-1}×L slab geometry with an aspect ratio ρ=L/L_{∥}>0 and for film geometry (ρ=0). Good overall agreement is found with Monte Carlo (MC) data for isotropic spin models with n=1,2,3. For ρ=0, the low-temperature limits of F^{ex} and X vanish for n=1, whereas they are finite for n≥2. For ρ>0 and n=1, we find a finite low-temperature limit of F^{ex}, which deviates from that of the Ising model. We attribute this deviation to the nonuniversal difference between the φ^{4} model with continuous variables and the Ising model with discrete variables. For n≥2 and ρ>0, a logarithmic divergence of F^{ex} in the low-temperature limit is predicted, in excellent agreement with MC data. For 2≤n≤∞ and ρ<ρ_{0}=0.8567 the Goldstone modes generate a negative low-temperature Casimir force that vanishes for ρ=ρ_{0} and becomes positive for ρ>ρ_{0}. For anisotropic systems a unified hypothesis of multiparameter universality is introduced for both bulk and confined systems. The dependence of their scaling functions on d(d+1)/2-1 microscopic anisotropy parameters implies a substantial reduction of the predictive power of the theory for anisotropic systems as compared to isotropic systems. An exact representation is derived for the nonuniversal large-distance behavior of the bulk correlation function of anisotropic systems and quantitative predictions are made. The validity of multiparameter universality is proven analytically for the d=2,n=1 universality class. A nonuniversal anisotropy-dependent minimum of the Casimir force scaling function X is found. Both the sign and magnitude of X and the shift of the film critical temperature are affected by the lattice anisotropy.