Abstract
The crosslinking yields in narrow molecular weight distribution polystyrene bombarded with H + and noble gas ions at energies of 100–400 keV have been compared with yields computed from literature data. The data have been plotted vs the linear energy deposition of the bombarding ions and a threshold located at ca. 10 eV/Å has been found. This curve has been discussed and explained in terms of energy deposited along the ion track and in terms of type and concentration of intermediate chemical species produced by the particle beam passage.
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