Abstract
In this work, high-temperature shape memory polymers are realized by end-group crosslinking of the semiaromatic polyesters polyethylene terephthalate as well as polybutylene terephthalate. Both networks exhibit trigger temperatures distinctly higher than 200 °C and excellent shape memory properties such as storable strains of 200%, full fixity of the applied strain in the temporary shape, and full recovery of the permanent shape.
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