Abstract
The synthesis of a well defined poly(ethylene oxide) network is described. This was achieved by performing hydrosilylation of α,ω-diallyl PEO with 2,4,6,8-tetramethyltetrahydrocyclosiloxane (D 4H). The influence of several factors, including the nature of the catalyst, temperature, (SiH)/(double bond) ratio and traces of water, on the hydrosilylation reaction is described. Side reactions were studied by 1H and 29Si n.m.r.
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