Cross‐linking and foaming behavior of elastomers with water based blowing agents

Abstract

AbstractPhysiologically hazardous chemical blowing agents are state of the art for the foaming of extruded rubber profiles. Water is a potential alternative to these blowing agents and is incorporated into rubber compounds in the form of water‐loaded hygroscopic substances such silica or hydrates. To achieve an optimum foaming result, the water desorption and cross‐linking reaction has to be coordinated. Studies of the foaming behavior in the salt bath of the Sponge Rubber Analyzer show, that the density of an ethylene propylene diene monomer (EPDM) rubber compound is reduced to about 60% and a nitrile butadiene rubber (NBR) compound to approximately 70%. The low reference densities of chemically foamed EPDM of 30% and NBR of 45% are not achieved. This is attributed to the premature foaming when using water‐loaded silica as blowing agent. Due to the low resistance of the rubber matrix, large cells are formed by coalescence, which collapse at low cross‐linking densities. Investigations of the cross‐linking behavior of EPDM and NBR with water‐loaded silica as blowing agent state, that the cross‐linking density is reduced to about 65% for EPDM and 50% for NBR when water is present. Furthermore, the incubation time is shortened by inhibition of the CBS retarder in the cross‐linking system of the NBR. However, this is not sufficient to fix the foamed cells.