Cross-interface transfer of polycyclic aromatic hydrocarbons (PAHs) in a shallow urban lake in Shanghai, China based on the fugacity model

Abstract

Shallow urban lakes are important urban ecosystems; however, these systems are subject to severe polycyclic aromatic hydrocarbons (PAHs) contamination. An understanding of the distribution and dynamics of PAHs in lakes is required to restore the functions of lake ecosystems and to ensure the ecological security of urban water sources. The Quantitative Water Air Sediment Interaction (QWASI) model and partition coefficient and fugacity fraction methods were applied to estimate the multimedia transfers of PAHs in Dianshan Lake, a typical shallow lake in Shanghai, China. In addition, some new concepts and methods related to PAH transfers were introduced. The results showed that while the gas-solid partition in the area remained in non-equilibrium, the influence of pollution sources tended to weaken. Atmospheric advection was the main source of PAHs to the lake, and a portion of the net loss of advection was transformed into total flux of cross-interface transfers, in which transport fluxes from air to water and from water to sediment were dominant, with a significant correlation between the two types of transfer. The large resuspension of high molecular weight (HMW)-PAHs occurred, possibly related to frequent hydrodynamic disturbances. Furthermore, this study explored the distribution of PAHs among different compartments and the seasonal variation of multimedia transfers. Sensitivity analysis showed that the model is remarkably sensitive to four parameters including temperature and advection. Monte Carlo uncertainty analysis verified that the simulation results were stable and reliable. The results can provide a theoretical basis for the monitoring and control of shallow lake pollution.