Critical viscosity exponent for classical fluids

Abstract

A self-consistent mode-coupling calculation of the critical viscosity exponent z(eta) for classical fluids is performed by including the memory effect and the vertex corrections. The incorporation of the memory effect is through a self-consistency procedure that evaluates the order parameter and shear momentum relaxation rates at nonzero frequencies, thereby taking their frequency dependence into account. This approach offers considerable simplification and efficiency in the calculation. The vertex corrections are also demonstrated to have significant effects on the numerical value for the critical viscosity exponent, in contrast to some previous theoretical work which indicated that the vertex corrections tend to cancel out from the final result. By carrying out all of the integrations analytically, we have succeeded in tracing the origin of this discrepancy to an error in earlier work. We provide a thorough treatment of the two-term epsilon expansion, as well as a complete three-dimensional analysis of the fluctuating order-parameter and transverse hydrodynamic modes. The study of the interactions of these modes is carried out to high order so as to arrive at z(eta) = 0.0679+/-0.0007 for comparison with the experimentally observed value, 0.0690+/-0.0006 .