Abstract

When the ground state of a localized ion is a non-Kramers doublet, such localized ions may carry multipolar moments. For example, Pr$^{3+}$ ions in a cubic environment would possess quadrupolar and octupolar, but no magnetic dipole, moments. When such multipolar moments are placed in a metallic host, unusual interactions between these local moments and conduction electrons arise, in contrast to the familiar magnetic dipole interactions in the classic Kondo problem. In this work, we consider the interaction between a single quadrupolar-octupolar local moment and conduction electrons with $p$-orbital symmetry as a concrete model for the multipolar Kondo problem. We show that this model can be written most naturally in the spin-orbital entangled basis of conduction electrons. Using this basis, the perturbative renormalization group (RG) fixed points are readily identified. There are two kinds of fixed points, one for the two-channel Kondo and the other for a novel fixed point. We investigate the nature of the novel fixed point non-perturbatively using non-abelian bosonization, current algebra and conformal field theory approaches. It is shown that the novel fixed point leads to a, previously unidentified, non-Fermi liquid state with entangled spin and orbital degrees of freedom, which shows resistivity $\rho \sim T^{\Delta}$ and diverging specific heat coefficient $C/T \sim T^{-1 + 2\Delta}$ with $\Delta=1/5$. Our results open up the possibility of myriads of non-Fermi liquid states, depending on the choices of multipolar moments and conduction electron orbitals, which would be relevant for many rare-earth metallic systems.

Highlights

  • Quantum theory of metals is often discussed in the framework of Fermi liquid, where well-defined fermionic quasiparticles dominate thermodynamic and transport properties

  • The classic Kondo problem [3,4,5], where the local magnetic dipole moment of a single localized ion interacts with conduction electrons’ spin, is one prominent example where the dichotomy between Fermi liquid and non-Fermi liquid behaviors can be seen [6,7]. We call this the dipolar Kondo problem to clearly distinguish it from the model that we study in this work

  • We demonstrate the existence of a novel non-Fermi liquid state in the multipolar Kondo problem, where the local moment is characterized by a non-Kramers crystal-field doublet that carries multipolar moments such as quadrupolar or octupolar moments

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Summary

INTRODUCTION

Quantum theory of metals is often discussed in the framework of Fermi liquid, where well-defined fermionic quasiparticles dominate thermodynamic and transport properties. We demonstrate the existence of a novel non-Fermi liquid state in the multipolar Kondo problem, where the local moment is characterized by a non-Kramers crystal-field doublet that carries multipolar moments such as quadrupolar or octupolar moments While such multipolar moments are abundant in quantum materials with f-electron moments [25,26,27,28,29], the corresponding Kondo problem [30,31,32] has not been fully understood. This leads to singular behavior for experimentally relevant quantities, such as the specific heat coefficient C=T ∼ T−1þ2Δ 1⁄4 T−3=5 and the resistivity ρ ∼ TΔ 1⁄4 T1=5 This represents a rare example of solvable non-Fermi liquid fixed points. Our work provides a concrete example of the possibility of a wide variety of Kondo effects, as well as a myriad of non-Fermi liquids, which may arise in rare-earth metallic compounds

MICROSCOPIC MODEL
SPIN-ORBIT COUPLED BASIS FOR CONDUCTION ELECTRONS
Two-channel Kondo fixed point
Novel fixed point
INSTABILITY OF STRONG-COUPLING LIMIT
CURRENT ALGEBRA APPROACH TO NOVEL FIXED POINT
MAVERICK COSET CONSTRUCTION
VIII. FINITE-SIZE SPECTRUM
PHYSICAL PROPERTIES
DISCUSSIONS
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