Abstract

We present a comprehensive study concerning the light exposure of bare Cu(In,Ga)Se2 (CIGSe) layers in ambient air and its impact on the electrical properties of the solar cells. With time-resolved photoluminescence (TRPL) a degradation of the minority charge carrier lifetime after air-light exposure of CIGSe layers is observed. This degradation is related to a light induced modification of the CIGSe surface and persists upon completion of the solar cells. A strong reduction in solar cell performance from ∼16% down to ∼13% reflects the degradation effect of the solar cell’s absorber. The deteriorated solar cell performance can be recovered by light soaking of the complete solar cell at increased temperatures of 85 °C.

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