Critical properties in La0.7Ca0.2Sr0.1MnO3 manganite: A comparison between sol-gel and solid state process

Abstract

The critical properties of La0.7Ca0.2Sr0.1MnO3 manganite elaborated using two different methods have been investigated around the ferromagnetic-paramagnetic phase transition. Our sample was successfully synthesized by solid-state reaction (S1) and sol-gel route (S2). The X-ray diffraction characterizations show that (S1) crystallized in orthorhombic structure with Pnma space group without any detectable impurity. Though, (S2) crystallized in rhombohedra structure with R-3C space group. Various techniques such as modified Arrott plots, Kouvel-Fisher method and critical isotherm analysis were used to determine the values of the Curie temperature TC, as well as the critical exponents β (corresponding to the spontaneous magnetization), γ (corresponding to the initial susceptibility) and δ (corresponding to the critical magnetization isotherm). The estimated results are close to those expected by the mean-field model for sample S2; while for sample S1, the exponents values are close to those expected using the tricritical model. The obtained values from critical isotherm M (TC, μ0H) are close to those determined using the Widom scaling relation, and also there are found to follow scaling equation with the magnetization data scaled into two different curves below and above TC, which implies the reliability and accuracy of the exponents. The change of the universality class can be explained by the reduction of the grain size. These results show that the critical behavior of our sample depend havely on the synthesis technique.