Abstract
Ab initio quantum modeling is applied to calculate the equation of state and the proton–proton pair correlation functions in the range of hydrogen temperatures and densities where the fluid–fluid phase transition is expected. The estimation of the critical temperature of the fluid–fluid phase transition in warm dense hydrogen is obtained Tc ⩾ 4000 K. A two-step mechanism of the phase transition is suggested: the partial ionization of molecules to produce molecular ions .
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