Critical flux analyses on differently pretreated olive vegetation waste water streams: Some case studies

Abstract

One of the main disadvantages of batch membrane processes is the increase of the pollutant concentration in the feedstock throughout the operation. Operating the plant at constant process conditions leads in many cases to weaker performances and, moreover, to heavy fouling on the membranes. Critical flux-based methods are one of the most used approaches to overcome fouling problems. Within critical flux conditions, only reversible fouling can occur, which can be periodically soft-cleaned. This work studies the relationship between particle size distributions in the feed stream and critical flux values when different pretreatment processes are applied to an olive vegetation waste water stream. The considered pretreatment processes were: coagulation (with aluminum hydroxide and aluminum sulphate), aerobic biodigestion (by means of fungi) and photocatalytic organic matter reduction (by means of nanometric titanium dioxide anatase powders irradiated by UV light). The study was carried out at pilot plant scale (100 L batch capacity). These results were compared with performances and effects on the critical flux value for MF, UF and NF membranes. The different pretreatment on the same waste water stream shifts differently the particle size distribution mainly by organic matter degradation, and this influences heavily the critical flux value and thus the filtration outcome. Finally, the purification of the olive vegetation waste water stream can be performed with a MF, UF, NF and RO membrane system in series, being very careful in choosing the correct operating conditions to avoid the quick formation of an unsustainable fouling.