Critical current and upper critical field of sintered and powdered superconducting YBa2Cu3O7

Abstract

A sintered bulk sample of YBa2Cu3O7 has been investigated resistively and inductively with respect to its resistivity ϱ(B, T), upper critical fieldBc2(T), and current carrying capabilityjc(B, T). The inductive measurements were repeated after powdering the sample to a maximum particle size of 60 μm. Results show that the intrinsic-intragrain properties as approximately revealed by the powder measurements, are severely masked in bulk measurements by the intergrain weak-link structure. As an example, the current densityjc(≃0 T, 4.2 K) in the powdered YBa2Cu3O7 has a value of 4·106 A/cm2, which is about three orders of magnitude higher than in the bulk material. The high values of the intragrainjc are probably due to pinning at twin boundaries. — Besidesjc the normal state resistivity just aboveTc, ρn, is influenced by the interconnecting structure, both properties being directly related: a smaller ρn leads to a higherjc in bulk samples. — The upper critical field shows a pronounced anisotropyBc2|/Bc2⊥ of about 20 to 30, whereBc2|=330 T is the extrapolated upper critical field at zero temperature for the field orientation parallel to the (Cu−O)-planes. — For the time being, theBc2 anisotropy and the weak-link structure of sintered bulk samples are the main obstacles for high field applications.