Critical behavior and room temperature magnetocaloric effect of La-doped Pr0.7Sr0.3MnO3 compounds

Abstract

In this work, we present the critical and the magnetocaloric properties of Pr0.7-xLaxSr0.3MnO3 compounds around room temperature. The samples exhibit a single phase with an orthorhombic structure. However, the lattice parameters increase with an increase in La content (x). The Curie temperature (TC) of the ferromagnetic (FM)-paramagnetic (PM) phase transition of compounds increases from 256 K for x = 0–319 K for x = 0.3. We observed a large magnetocaloric effect with high maximum magnetic entropy change (|ΔSmax|) values occurring around room temperature, corresponding to |ΔSmax| = 6.65 and 5.21 J/kgK under a magnetic field change (ΔH) of 50 kOe for x = 0.2 and 0.3, respectively. We also pointed out that the change in |ΔSmax| obeys an exponential function of ΔH (|ΔSmax| ∼ ΔHn), where the value of field exponent (n) is approximately 0.52. Furthermore, the critical behavior around TC for compounds with x = 0.2 and 0.3 has been investigated. The results indicate that these compounds undergo a second-order phase transition with the critical parameters (β = 0.311, γ = 1.137, and δ = 4.656 at TC = 298.4 K for x = 0.2; and β = 0.319, γ = 1.098, and δ = 4.442 at TC = 318.7 K for x = 0.3) that are quite close to those expected for the 3D-Ising model. This suggests the existence of the short-range magnetic interactions in these compounds.