Abstract
Chloride-induced crevice corrosion of a 316L pump was found to have occurred in what was nominally a very dilute solution of sodium chloride in a single-phase solution of water in butanone at 25°C. The hypothesis formed was that water had entered the system in a sufficient amount to form an immiscible mixture of a water-rich phase and a butanone-rich phase. This separation into two liquids was followed by preferential partition into the water-rich phase of the sodium chloride to give a brine. A simple test demonstrated that the hypothesis was tenable.
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