Creep Viscosity and Stress Relaxation of Gel‐Derived Silicon Oxycarbide Glasses

Abstract

The temperature dependence of the viscosity and stress‐relaxation kinetics of sol–gel‐derived SiOC glasses that contain up to 14 at.% carbon have been characterized in the temperature range of 1000°–1400°C. The viscosity, as determined from relaxation experiments, is in good agreement with the creep viscosity and is typically two orders of magnitude higher than the viscosity of vitreous silica. However, materials suffer from partial crystallization at >1150°C, and the precipitation of β‐SiC nanocrystals induces a flow‐hardening behavior and results in a dynamic increase in viscosity, especially at >1200°C and for glasses with a high carbon content.