Abstract

The creep of the newly developed Ni-based, Re free, single crystal superalloy NKH71 was examined at 1273 K. The creep properties were compared to those of CMSX-4, a second-generation commercial superalloy containing 3%Re. When the (applied) stress was higher than 160 MPa, the rupture lives of the present alloy were shorter than those of CMSX-4. However, when the stress was below 160 MPa, the rupture lives of the present alloy became longer than those of CMSX-4. It was noted that this lower stress level was more important when Ni-based superalloys were used for engineering land-based gas turbines. TEM and SEM observations showed that NKH71 formed a rafted structure in the early stage of creep. This was because a large number of dislocations existed in the γ / γ ′ interfaces before creep. In contrast, CMSX-4 had very few dislocations before creep. This observation explained why NKH71 was inferior to CMSX-4 under high stress. However under lower stress, the γ / γ ′ rafted structure changed to a more complex morphology in CMSX-4, while that of NKH71 tended to remain unchanged. This conservation of the rafted structure lead to the good creep resistance of NKH71 under a lower stress. In brief, the new alloy was shown to have good creep resistance even without Re element.

Highlights

  • Turbine inlet gas temperature of land-based gas turbines have increased to improve thermal efficiency and to reduce SOx, NOx and CO2 emissions [1]

  • Undesirable topologically close packed (TCP) phases are formed at higher temperatures in this kind of alloy [2,3,4]

  • The present paper reports creep properties of NKH71 at 1273 K in comparison with CMSX-4

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Summary

Introduction

Turbine inlet gas temperature of land-based gas turbines have increased to improve thermal efficiency and to reduce SOx, NOx and CO2 emissions [1]. Ni-based superalloys can be used for this purpose. Re-containing Ni superalloys, have been used for aero turbine blades, since these alloys showed improved creep resistance. We aimed to eliminate Re from Ni-based superalloys. The present alloy, NKH71, was produced for this purpose [5]. This alloy shows good creep resistance, equal to or better than conventional second-generation Re-containing alloys such as CMSX-4. The present paper reports creep properties of NKH71 at 1273 K in comparison with CMSX-4

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