Creation of Carbazole-Based Fluorescent Porous Polymers for Recognition and Detection of Various Pesticides in Water.

Abstract

The development of sensitive, fast, and portable methods for detecting the residual toxic pesticides is essentially important because of the increasing concerns for public health and safety. For this purpose, three fluorescent porous organic polymers containing pendant N-benzyl carbazole, N-benzyl dibromo-carbazole, and N-benzyl dimethoxy-carbazole groups were synthesized via a one-step polymerization reaction. The resultant polymers emit bright cyan, blue, and green light under the ultraviolet lamp, respectively, with the Brunauer-Emmett-Teller area up to 858 m2 g-1 and tunable pore sizes in the range of 0.5-36 nm. Six pesticides including trifluralin, isopropalin, glyphosate, fenitrothion, imidacloprid, and cyfluothrin are selected as the analytes to investigate the recognition and detection ability of polymers in terms of the different photo-physical properties of polymers, chemical structure of organic pesticides as well as the pore sizes of polymers, and molecular sizes of pesticides. It is interesting to find that, even though in water medium, the measured fluorescent quenching Stern-Volmer coefficient for trifluralin still reaches 26,040 L mol-1 and is nearly unchanged under both acidic or basic service conditions. Moreover, the test paper prepared from the polymer exhibits a rapid fluorescent response when contacting the aqueous trifluralin dispersion liquid, and the sensitivity remains stable after recycling use for twelve times.