Crater Lake Kipyashchee of Volcan Golovnin Caldera: Geochemistry of Water and Gases, Output of Magmatic Volitatives (Kunashir Island)

Abstract

Lake Kipyashchee (Boiling) with an area of ~4.6 ha and a maximum depth of 25 m fills the explosion funnel near one of the extrusive domes of the Golovnin volcano caldera. The water of the lake is ultra-acid (рН = 2.2–2.5) of the chloride-sulfate type with a mineralization of 2.0–2.2 g/l. The water temperature on the surface varies from 30 to 100°C, the average is 37°C. The flow of the lake is carried out through the Protoka in the lake Goryachee (Hot) is 120 l/s (August 2021). The hydrothermal output of magmatic Cl and S (as SO4) from Lake Kipyashchee is 10 t/day and 5.4 t/day, respectively. For the first time, the total diffusive removal of carbon dioxide from the surface of Lake Kipyashchee was estimated as 5.4 tons/day. Obtained from the results of field work in 2020–2021 geochemical data indicate an increase (compared to 2015) in hydrothermal activity in the Golovnin volcano caldera.