Cr3+‐doped far‐red phosphors with zero thermal quenching and excellent spectral matching for plant lighting application

Abstract

AbstractFar‐red‐emitting (700−740 nm) phosphors are essential for the fabrication of plant lighting phosphor‐converted light‐emitting diodes (pc‐LEDs). However, the development of highly efficient, thermally stable, and spectrally matched far‐red phosphors still remains a challenge. Herein, far‐red GdAlO3:Cr3+ (GAO:Cr3+) phosphors were synthesized via solid‐state reaction and investigated for plant lighting pc‐LED applications. A low‐temperature flux‐assisted synthesis strategy was adopted to improve the crystalline quality, suppress the defect formation, and maintain the valence state of Cr3+ in the phosphors, finally leading to significant luminescent enhancement (∼10 times). The GAO:Cr3+ phosphors show the 2E sharp‐line emissions around 730 nm, which is highly matched with the far‐red absorption band of plants. The optimized GAO:0.01Cr3+ phosphor exhibits a high internal quantum efficiency of 98.3% and zero thermal quenching even up to 250°C. The fabricated pc‐LED can generate an overall output power of 78.1 mW at 100 mA drive current, with a high energy conversion efficiency of 25.3%. The findings demonstrate the great potential of GAO:Cr3+ as far‐red‐emitting phosphor materials for plant growth pc‐LED applications.