Abstract

Supercritical water possesses vastly different properties compared to its liquid phase, for instance it is well known that the famous tetrahedral H-bond network is destroyed. In their Research Article on page 18578, P. Schienbein and D. Marx further unveil that supercritical water should not be considered as a H-bonded fluid at all due to ultrafast reorientational dynamics on the timescale of intermolecular H-bond vibrations. Instead, it behaves much like an isotropic van der Waals fluid.

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