Abstract
Precisely adjusted solvates. influence the oxidation potential of substrates for the electrochemical cross-coupling of arenes. The solvent mixture based on 1,1,1,3,3,3-hexafluoroisopropanol (HFIP) and MeOH gives rise to a decoupling of nucleophilicity from the oxidation potential. In their Full Paper on page 12321 ff., S. R. Waldvogel and co-authors rationalize the outstanding selectivity of the anodic cross-coupling. This solvent effect explains also the selectivity previously found by HFIP mixtures. Precisely adjusted solvates. influence the oxidation potential of substrates for the electrochemical cross-coupling of arenes. The solvent mixture based on 1,1,1,3,3,3-hexafluoroisopropanol (HFIP) and MeOH gives rise to a decoupling of nucleophilicity from the oxidation potential. In their Full Paper on page 12321 ff., S. R. Waldvogel and co-authors rationalize the outstanding selectivity of the anodic cross-coupling. This solvent effect explains also the selectivity previously found by HFIP mixtures. Pincer catalysts Amino Acids for Live-Cell Labeling Bimetallic Tadpoles
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