Abstract
The hydroazidation of unactivated alkynes is described by X. Bi and co-workers in their Communication on page 5305 ff. Silver catalysis enabled the chemo- and regioselective transformation of ethynyl carbinols into vinyl azides. A wide variety of 2-azidoallyl alcohols were obtained in good to excellent yields. The synthetic utility of 2-azidoallyl alcohols was demonstrated by further transformations into NH aziridines.
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