Abstract
AbstractThe computational study of gold(I)‐catalyzed ring expansion reactions of unactivated alkynylcyclopropanes is reported. The main finding of this work is that when unactivated alkynylcyclopropane with a smaller singlet‐triplet splitting (ΔEST) is utilized, the gold(I)‐catalyzed ring expansion step has a smaller activation energy and a larger exothermicity. For more information about this figure, turn to pp 473∼480 in this issue.
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