Abstract
Polyoxometalates or POM are remarkable because of their molecular and electronic tunability, and their range of properties and applications. In their Full Paper on page 9150 ff., E. A. Maatta, A. Proust et al. discuss various routes to nitrido derivatives, which may act as nitrogen‐atom transfer reagents to organic substrates. 183W and 15N NMR, EPR, IR, and UV/Vis spectroscopies and cyclic voltammetry have been used to address their electronic and molecular structures.
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