Cover Picture: Amine‐Tagged Fragmented Ligand Installation for Covalent Modification of MOF‐74 (Angew. Chem. Int. Ed. 17/2021)

Abstract

Amine-tagged defective Ni-MOF-74 was prepared by solvothermal synthesis using aminosalicylic acid as a functionalized fragmented ligand, as described by Seung Bin Baek, Myoung Soo Lah et al. in their Communication on page 9296. The covalent post-synthetic modification and subsequent post-synthetic metalation with palladium(II) ions affords a palladium(II)-incorporated Ni-MOF-74 catalyst, which exhibits highly efficient, size-selective, and recyclable catalytic activity for the Suzuki–Miyaura coupling reaction. Amine-tagged defective Ni-MOF-74 was prepared by solvothermal synthesis using aminosalicylic acid as a functionalized fragmented ligand, as described by Seung Bin Baek, Myoung Soo Lah et al. in their Communication on page 9296. The covalent post-synthetic modification and subsequent post-synthetic metalation with palladium(II) ions affords a palladium(II)-incorporated Ni-MOF-74 catalyst, which exhibits highly efficient, size-selective, and recyclable catalytic activity for the Suzuki–Miyaura coupling reaction. Cisplatin Cell Imaging Phosphors