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Abstract
Cationic T‐shaped platinum complexes are obtained because of the high trans influence of the ferrocenyl(bromo)boryl ligand. Addition of 4‐methylpyridine to the platinum(II) boryl complex (as shown in the cover picture) causes displacement of the bromide ion at boron, leading to a cationic platinum complex with a 4‐methylpyridine‐stabilized borylene ligand (bottom right). For more information on this approach, see the Communication by H. Braunschweig et al. on page 5651 ff.
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