Abstract
An organometallic uranium bimetallic complex exhibits signatures of electronic delocalization. In their Full Paper on page 7782 ff., J. L. Kiplinger, D. E. Morris et al. have shown that multimetallic uranium and thorium architectures can be easily assembled by using nitrile insertion chemistry into actinide–carbon bonds. With its covalent metal–ligand bonds, the resulting 1,4-phenylenediketimide bridging ligand provides a useful platform for the study of metal–metal interactions. Electrochemistry of the thorium analogue affords definition of metal-based processes in the uranium bimetallic system.
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