Abstract
Bond activation: An unprecedented [2+1+1] fragmentation of the P4 tetrahedron and formation of an eight-membered M−P=Si−P=P−Si=P−M chain was achieved in reactions of white phosphorous with heteroleptic metallasilylenes. More information can be found in the Research Article by S. Schulz and co-workers (DOI: 10.1002/chem.202201031).
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