Abstract
Persistent radicals play an increasingly important role in synthesis and catalysis. Stabilization of radicals may be achieved by incorporation into a delocalized π-electron system, generating multiple potentially reactive sites. Using aminotroponiminates (ATIs) as a model system, this work addresses chemo-, regio-, and diastereoselectivities as well as equilibria in reactions of persistent radicals. Unexpectedly, dramatic differences in the reactivity of Li, Na, and K-ATIs were observed. More information can be found in the Full Paper by C. Lichtenberg et al. on page 11891.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.