Abstract
The Cover Feature shows an unusual 2D FeIII coordination network in which pairs of radical TCNQ anions are corralled within rectangular cavities. Electrical conductivity measurements reveal semiconducting behavior, which is supported by density functional theory calculations. Magnetic measurements are suggestive of weak antiferromagnetic coupling. Variable temperature Mossbauer spectroscopy indicates a rare example of the Goldanskii-Karyagin effect, which, along with structural data, is consistent with concerted movement of FeIII centers within the crystal lattice. Image courtesy of Owen Abrahams. More information can be found in the Communication by B. F. Abrahams, G. N. L. Jameson, R. Robson et al.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
