Abstract
Double impact: The use of both azide and di-2-pyridylketone-derived ligands has provided new Mn24 (left) and Mn26 complexes (right) with loop and dumbbell structures that are made up of two covalently linked Mn12 and Mn13 units, respectively. Both complexes are single-molecule magnets, and the Mn26 complex displays the largest barrier for magnetization reversal in a MnII/III complex known to date. MnII yellow, MnIII blue, O red, N green, C gray.
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