Abstract
This study explores an innovative photocatalytic approach using pristine graphitic carbon nitride (C3N4) to anchor iron salen-type complexes (FeSalenCl2) without the need for additional linkers or heterojunctions. The resulting hybrid catalyst, [C3N4-FeCl(Salen)]Chem, exhibits a promising catalytic performance in the selective epoxidation of cyclic and linear olefins using gaseous oxygen as the oxidant. The catalyst's selectivity closely resembles that of the free iron complex, and its effectiveness varies depending on the olefin substrate. Additionally, solvent selection plays a critical role in achieving optimal performance, with acetonitrile proving to be the best choice. The study demonstrates the potential of C3N4 as an environmentally friendly, recyclable, and efficient support for molecular catalysts. The results highlight the versatility and significance of C3N4-based materials in advancing light-driven catalysis.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
