Abstract
Cobalt carbonyl cluster was anchored through a facile route on the surface of organo-functionalized SBA-15 molecular sieve by post-synthetic approach. The successful grafting of organofunctional ligand and cobalt carbonyl cluster was evident thorough 29Si-MAS NMR, 13C-MAS NMR and FT-IR studies. The resultant cobalt clusters anchored functionalized SBA-15 material (SBA-15-RCo) showed promising catalytic activity on hydroformylation of 1-octene (97% conversion) with excellent selective towards hydroformylated products (90%).
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