Abstract
Abstract Bezier curves for the calculation of retention indices in temperature-programmed gas–liquid chromatography. Retention indices of eleven organochlorine species, separated by temperature-programmed gas chromatography, computed by smoothing reference data with Bezier curves of orders 7 and 10 are more consistent with the scheme of this retention parameter, and present standard deviations systematically smaller than those associated with classical retention indices. These results are reproduced when solutes are referred to even alternate n-alkanes. © 2000 Academie des sciences / Editions scientifiques et medicales Elsevier SAS gas chromatography / temperature programming / smoothing of reference data / independent of local properties function
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