Abstract

Abstract An approximate method is presented for evaluating reduced vibrational coupling strengths for non-radiative transitions in aromatic hydrocabons. Magnitudes of the coupling strength in the low-temperature limit are estimated for the intramolecular non-radiative transitions 1B2u → 1A1g in benzene and 1B2u ??1? 1Ag, 1B1u → 1Ag, and 1B1u ⇝ 1B2u in naphthalene.

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