Abstract
An analysis of the 13CH satellite resonances in the NMR spectra of 1-substituted aziridines is reported. The interproton coupling constants as well as the 13CH couplings associated with the cis and trans ring methylene protons are separately determined. Considerably different values of vicinal cis HH coupling for the cis and trans protons as well as the corresponding directly bonded 13CH coupling are obtained. The effect of the orientation of the nitrogen lone pair on the adjacent 13CH coupling constant is also discussed.
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