Abstract
The use of CH4 and CO2 to produce value-added chemicals via direct C-C coupling is a challenging chemistry problem because of the inertness of these two molecules. Herein, mass spectrometric experiments and high-level quantum-chemical calculations have identified the first diatomic species (CuB+ ) that can couple CH4 with CO2 under thermal collision conditions to produce ketene (H2 C=C=O), an important intermediate in synthetic chemistry. The order to feed the reactants (CH4 and CO2 ) is important and CH4 should be firstly fed to produce the C2 product. Molecular-level mechanisms including control of product selectivity have been revealed for coupling of CH4 with CO2 under mild conditions.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
