Coupling of Fe-C and aerobic granular sludge to treat refractory wastewater from a membrane manufacturer in a pilot-scale system

Abstract

A novel pilot-scale system based on aerobic granular sludge (AGS) as a biological treatment step was proposed to treat refractory wastewater from a membrane manufacturer. The components of the system included a microelectrolysis Fe-C filter, a hydrolysis acidification bioreactor (HA), sequence batch reactor 1 (AGS SBR1), sequence batch reactor 2 (AGS SBR2), and a membrane bioreactor (MBR). The Fe-C filter effectively improved the biodegradability of the wastewater components and introduced some byproducts (such as Fe2+, Fe3+, and Fe minerals) that are beneficial for the cultivation and stability of the AGS. Ideal conditions for aerobic granulation were maintained in the SBR, such as alternating feast and famine conditions. A selection pressure, including a hydraulic shear force and settling time, was also created therein. The results showed that the AGS was formed successfully in both SBR1 and SBR2, the sludge volume index after 30 min (SVI30) and mean particle size reached 34.2 mL/g and 720 µm, and 36.7 mL/g and 610 µm, respectively, and a satisfactory nutrient removal capacity was achieved in the system. During the entire experimental period, the microbial community changed significantly; enrichment of microbes with the secretion of extracellular polymeric substances (EPS), granule stabilization functions in the AGS, and the differentiation of microbes corresponding to the function of each unit were observed. The use of Fe-C, application of SBRs, and use of dewatered sludge as an inoculant played key roles in the cultivation and stability of the AGS.