Abstract
The pK HA and E ox (A - ) values of 29 α-substituted derivatives of acetone and acetophenone have been compared with those of the parents. The ΔpK HA and ΔE ox (A - ) values are summed to obtain ΔBDE values, which are equated with the radical stabilization energies (RSEs) of the corresponding radicals. Since the two equilibria defining pK HA and E ox (A - ) are linked to one another, either changes in pK HA or E ox (A - ) may play the major role in deciding the size of the RSEs caused by making the structural change
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