Abstract
The C–C bond-forming reaction by direct coupling of two chiral 17-electron metal vinyl units [Fe(C5Me5)(CO)(PMe3){C(OMe)CH2}]˙+ affords the µ-bis(carbene) dimetallic complex [{Fe(CBMe5)(CO)(PMe3)}2{µ-C(OMe)[CH2]2–C(OMe)}][PF6]25 with chiral recognition (major : minor = 2 : 1); the two diastereoisomers are isolated in a pure form.
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