Coupling between the photo-excited cyclic π system and the 4f electronic system in a lanthanide single molecule magnet.

Abstract

A new type of electronic interaction which couples two angular momenta, i.e. the angular momentum of a localized 4f system (J) and an orbital angular momentum generated in a cyclic π conjugated system by irradiation with a circularly-polarized light, has been identified in a lanthanide single molecule magnet.