Abstract

The influence of guest atoms on thermal conduction in filled skutterudites was studied using ultrafast reflectance spectroscopy. Different filling species cause coupled vibrational modes between the guest atoms and the host lattice at different frequencies, which scatter phonons in different spectral spans. Using a Debye model for the measured lattice thermal conductivity together with the measured vibration frequencies and scattering rates, it is shown that scattering due to the coupled vibrational modes has a considerable contribution to the suppression of lattice thermal conduction. This demonstrates that filling with multiple species can efficiently reduce the lattice thermal conductivity in skutterudites.

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