Coupled spin waves and crystalline electric field levels in candidate multiferroic ErFeO3

Abstract

We report an inelastic neutron scattering study of candidate multiferroic ErFeO3, a compound that has been previously reported to have three different magnetic states and undergoes signatures of Fe3+−Er3+ cooperative coupling. The spectrum at low energy transfer is dominated by excitations of the Er3+ character, even above the Er3+ antiferromagnetic ordering temperature of 4.5 K. In addition, a crystalline electric field excitation at 6 meV exhibits additional energy splitting upon cooling through 4.5 K with mode-dependent polarization. This indicates different moment directions for these modes, an interesting consequence of Cy ordering of the Er3+ moments.