Abstract

The validity of the semiclassical approximation is studied for a system comprising one quasiparticle coupled to a boson degree of freedom. Using a two-site Holstein model as an example, it is shown that the semiclassical approximation becomes exact in a nontrivial adiabatic limit. Furthermore, in the model`s polaron regime, there exists a hierarchy of time scales that rationalizes the quantum dynamics of the Holstein model. For the single-mode case considered, the discrete nonlinear Schroedinger equation is found to be valid only in a highly limited antiadiabatic regime.

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