Abstract

We report a computational study of rotationally predissociating resonance states of ArHO( 2Σ +, v=0) for total angular momentum zero and one, using fully converged, close-coupled, scattering calculations. The three-dimensional intermolecular potential surface we use is the semi-empirical one proposed by Schnupf. [Chem. Phys. Letters 189 (1991) 487]. The calculations are in accord with recent experimental results obtained by Lester. [J. Chem. Phys. 99 (1963) 6211]. Additional resonance states are predicted which have not been reported experimentally.

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