Abstract

The electronic structure of tetracyanoethylene (TCNE) has been studied both in its pristine state and upon stepwise rubidium intercalation, by UV and x-ray photoelectron spectroscopy as well as with theoretical calculations. The intercalated system may serve as a model for TCNE-based organometallic magnets, of which the electronic structure remains largely unknown. Rubidium is found to n-dope the TCNE molecules forming ${\mathrm{Rb}}^{+}{\mathrm{TCNE}}^{\ensuremath{-}}$ with almost complete charge transfer. Calculations show a spin splitting of the former highest occupied molecular orbital level upon Rb doping. We see no evidence for the formation of doubly charged TCNE molecules. A gap opens up at the Fermi energy for ${\mathrm{Rb}}^{+}{\mathrm{TCNE}}^{\ensuremath{-}}$ due to on-site Coulomb interactions. We estimate the on-site Coulomb interaction of amorphous TCNE doped with Rb to be \ensuremath{\sim}2 eV.

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