Coulomb clusters: melting and potential barriers

Abstract

Abstract The melting of two-dimensional and three-dimensional Coulomb micro- and macroclusters is studied. Temperature dependences of radial and angular square deviations of particles are investigated. The melting of microclusters has two stages : at lower temperature there is a transition from a frozen phase to a state with a rotatory reorientation of “crystalline” shells relative to each other, different pairs of shells melting at different temperatures. In the case of large N and high triangular symmetry inside the cluster, orientational melting takes place only for external pairs of shells. In this case external shells lose their order. At higher temperature a transition with a loss of radial shell order occurs. The origin of two-stage melting is in the smallness of the barrier energy relative to the rotation of shells in comparison with the barrier corresponding to the radial disordering of shells. It is shown also that the temperatures of orientational and total melting are at 5–15 times lower than the temperatures of disappearance of corresponding potential barriers. The influence of confinement anisotropy on the character of cluster melting is considered. It is found that at some degree of anisotropy the melting becomes one stage. The last is connected with an increase of the ratios of barriers of intershell rotation to barriers of jumps of a particle between the shells.