Abstract

Silicon nanowires (Si NWs) emerged in several application fields as a strategic element to surpass the bulk limits with a flat compatible architecture. The approaches used for the Si NW realization have a crucial impact on their final performances and their final cost. This makes the research on a novel and flexible approach for Si NW fabrication a crucial point for Si NW-based devices. In this work, the novelty is the study of the flexibility of thin film metal-assisted chemical etching (MACE) for the fabrication of Si NWs with the possibility of realizing different doped Si NWs, and even a longitudinal heterojunction p-n inside the same single wire. This point has never been reported by using thin metal film MACE. In particular, we will show how this approach permits one to obtain a high density of vertically aligned Si NWs with the same doping of the substrate and without any particular constraint on doping type and level. Fractal arrays of Si NWs can be fabricated without any type of mask thanks to the self-assembly of gold at percolative conditions. This Si NW fractal array can be used as a substrate to realize controllable artificial fractals, integrating other interesting elements with a cost-effective microelectronics compatible approach.

Highlights

  • IntroductionSilicon nanowires (Si NWs) are emerging as a promising resource in different fields such as electronics [1,2,3,4,5], photovoltaics [6,7,8,9,10], and recently, photonics [11,12,13,14,15,16] and sensing [17,18,19,20,21]

  • We demonstrate that the interesting characteristics of a cost-effective, fast, industrially compatible, and flexible synthesis of metal-assisted chemical etching (MACE) can be coupled with a quantum confinement suitable dimension and fractal array organization by our synthesis

  • Si NWs were synthesized according to the thin film MACE process as described in the Materials and Methods section

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Summary

Introduction

Silicon nanowires (Si NWs) are emerging as a promising resource in different fields such as electronics [1,2,3,4,5], photovoltaics [6,7,8,9,10], and recently, photonics [11,12,13,14,15,16] and sensing [17,18,19,20,21]. The approaches used for Si NW realization have a crucial impact on the final performances in all these application fields and determine the final device cost [22]. This makes the research on a novel and flexible approach that can push the Si NW performance a crucial point for.

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